The post-install script will create an user and a group called `guixbuild`. If you want more users for building packages, add more users to the `guixbuild` group. Start the `guix-daemon` by using systemd or manually running command `guix-daemon --build-users-group=guixbuild` as root. `guix-daemon` will create most necessary files and directories when you first using it. If you want to use prebuilt packages provided by [GNU Hydra](http://hydra.gnu.org), you should run `guix archive --authorize --import < /usr/share/guix/hydra.gnu.org.pub` as root before using `guix package`.