The post-install script will create an user and a group called `guixbuild`. If you want more users for building packages, add more users to the `guixbuild` group. Start the `guix-daemon` by using systemd or manually running command `guix-daemon --build-users-group=guixbuild` as root. `guix-daemon` will create most necessary files and directories when you first using it. If you want to use prebuilt packages, you should run `for i in /usr/share/guix/*.pub; do guix archive --authorize < "$i"; done` as root before using `guix package`.